| 10:00 AM | Simona Halep (ROU) [21] vs. Flavia Pennetta (ITA) |
| 10:00 AM | Camila Giorgi (ITA) vs. Roberta Vinci (ITA) [10] |
| 11:30 AM | Ana Ivanovic (SRB) [13] vs. Victoria Azarenka (BLR) [2] |
| 1:30 PM | Roger Federer (SUI) [7] vs. Tommy Robredo (ESP) [19] |
| 6:00 PM | Philipp Kohlschreiber (GER) [22] vs. Rafael Nadal (ESP) [2] |